Heterogeneous catalysts are considered one of the key technologies as the chemical industry seeks to become more sustainable. The ‘Green Chemistry’ allowed by the use of such materials offers significant environmental as well as operational benefits to chemical processes, which are pivotal to the pharmaceutical, biotechnology, fine chemical and petrochemical sectors.
PhosphonicS™ has designed and developed a portfolio of heterogeneous catalysts, based on functionalised silicas, for metal-mediated oxidations, acid-promoted reactions and metal-mediated cross coupling reactions. These highly effective and selective catalysts can be easily filtered off, washed and recycled.
A developing range of Immobilised Enzymes are also in development
Immobilised ligands such as phosphines are also available
| Acid catalysts |
Metal Phosphonate Oxidation Catalysts |
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| Metal cross-coupling catalysts |
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Properties of PhosphonicSTM Heterogeneous Catalysts
- High Catalytic Activity
- High or Low Functional Group Loading possible, as required for particular applications
- Recycling options; multiple cycles without loss of activity
- Broad solvent compatibility
- Clean reactions, few by-products
- Availability on Process scale
- No detectable metal leaching
- No pre-swelling of the materials are required
- Excellent stability - thermal, physical, chemical and mechanical
Performance Benefits of PhosphonicSTM Heterogeneous Catalysts
- Improved : manufacturing economics, process design, waste burden
- Faster : purification, batch processing
- Enhanced : productivity, compliance to environmental standards
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